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Data Publication

Experimental adsorption parameters of boron isotopes on clay minerals

Ring, Simon J. | Henehan, Michael J. | Blukis, Roberts | von Blanckenburg, Friedhelm

GFZ Data Services

(2024)

Descriptions

Adsorption and isotopic fractionation of boron on clastic sediment is one process responsible for the heavy boron isotopic composition of the modern ocean. However, the mechanism by which boron complexes to the surface of clay minerals and the cause of its isotopic fractionation are still unclear. We performed two sets of experiments, using solutions of pure water with added boron and seawater, to explore the isotope behavior during adsorption of boron onto kaolinite, smectite and illite. The dataset consists of an excel file with four sheets that store (1) the NIST RM 803 measurements we used to establish the long-term reproducibility of our isotope measurements, (2) results of our pure experiment, (3) results of our seawater experiments and (4) a global compilation of XRD-based riverine clay mineral assemblages.

Keywords


Originally assigned keywords
surface complexation model
clay
boron isotopes
boron adsorption
compound material > sedimentary material > sediment > clastic sediment > mud > clay
EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > SUSPENDED SOLIDS
EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > SURFACE WATER > SURFACE WATER CHEMISTRY
In Situ/Laboratory Instruments > Spectrometers/Radiometers > MC-ICP-MS
physicochemical process > sorption > adsorption
The Present

Corresponding MSL vocabulary keywords
clay
clay

MSL enriched keywords
minerals
silicate minerals
phyllosilicates
clay
unconsolidated sediment
clastic sediment
clay
measured property
boron
illite
clay - kaolinite
kaolinite
clay - smectite
Technique
imaging (3D)
computed tomography (CT)
X-ray diffraction

MSL enriched sub domains i

geochemistry
microscopy and tomography


Source publisher

GFZ Data Services


DOI

10.5880/gfz.3.3.2024.003


Creators

Ring, Simon J.

GFZ German Research Centre for Geosciences, Potsdam, Germany | Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

ORCID:

https://orcid.org/0000-0002-2645-185X

Henehan, Michael J.

GFZ German Research Centre for Geosciences, Potsdam, Germany | School of Earth Sciences, University of Bristol, Bristol, United Kingdom

ORCID:

https://orcid.org/0000-0003-4706-1233

Blukis, Roberts

Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany

ORCID:

https://orcid.org/0000-0003-2999-0784

von Blanckenburg, Friedhelm

GFZ German Research Centre for Geosciences, Potsdam, Germany | Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

ORCID:

https://orcid.org/0000-0002-2964-717X


Contributors

Ring, Simon J.

ContactPerson

GFZ German Research Centre for Geosciences, Potsdam, Germany | Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

ORCID:

https://orcid.org/0000-0002-2645-185X

Ring, Simon J.

DataCollector

GFZ German Research Centre for Geosciences, Potsdam, Germany | Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

ORCID:

https://orcid.org/0000-0002-2645-185X

Ring, Simon J.

Researcher

GFZ German Research Centre for Geosciences, Potsdam, Germany | Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

ORCID:

https://orcid.org/0000-0002-2645-185X

Henehan, Michael J.

DataCollector

GFZ German Research Centre for Geosciences, Potsdam, Germany | School of Earth Sciences, University of Bristol, Bristol, United Kingdom

ORCID:

https://orcid.org/0000-0003-4706-1233

Henehan, Michael J.

Researcher

GFZ German Research Centre for Geosciences, Potsdam, Germany | School of Earth Sciences, University of Bristol, Bristol, United Kingdom

ORCID:

https://orcid.org/0000-0003-4706-1233

Henehan, Michael J.

Supervisor

GFZ German Research Centre for Geosciences, Potsdam, Germany | School of Earth Sciences, University of Bristol, Bristol, United Kingdom

ORCID:

https://orcid.org/0000-0003-4706-1233

Blukis, Roberts

Researcher

Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany

ORCID:

https://orcid.org/0000-0003-2999-0784

Blukis, Roberts

Supervisor

Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany

ORCID:

https://orcid.org/0000-0003-2999-0784

von Blanckenburg, Friedhelm

Supervisor

GFZ German Research Centre for Geosciences, Potsdam, Germany | Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

ORCID:

https://orcid.org/0000-0002-2964-717X

HELGES – Helmholtz-Laboratory For The Geochemistry Of The Earth Surface

HostingInstitution

GFZ German Research Centre for Geosciences, Potsdam, Germany

Ring, Simon J.

ContactPerson

GFZ German Research Centre for Geosciences, Potsdam, Germany


References

10.1346/ccmn.1981.0290305

10.1016/s0009-2541(02)00114-6

10.1016/j.epsl.2007.05.039

10.1346/ccmn.1985.0330509

10.1016/0016-7037(87)90285-7


Citation

Ring, S. J., Henehan, M. J., Blukis, R., & von Blanckenburg, F. (2024). Experimental adsorption parameters of boron isotopes on clay minerals [Data set]. GFZ Data Services. https://doi.org/10.5880/GFZ.3.3.2024.003


Dates

Issued:

2024


Funding References

Funder name: Deutsche Forschungsgemeinschaft

Funder identifier: 0000 0001 2096 9829

Funder identifier type: ISNI

Award number: 455982777


Rights

Creative Commons Attribution 4.0 International