Data Publication

Organochemical characterization of the mineralized Kupferschiefer in Spremberg, East Germany: Compositional and isotope data on hydrocarbons, biomarker and NSO compounds

Poetz, Stefanie | Liu, Yang | Magnall, Joseph M. | Vieth-Hillebrand, Andrea | Yang, Shengyu | Göthel, Michael | Gleeson, Sarah A. | Schulz, Hans-Martin | Karger, Cornelia | Noack, Doreen | Günther, Kristin | Kaminsky, Anke | Rothe, Heike

GFZ Data Services

(2022)

Descriptions

Organic matter (OM) is known to be an important reductant in sediment-hosted base metal deposits like the European Kupferschiefer. However, the precise nature of interactions between OM and hydrothermal fluids are still debated as well as how the interconnected reactions develop over geological timescales. This dataset provides for the first time bulk, compositional and stable isotope data of hydrocarbons, biomarkers and organonitrogen, -sulfur and-oxygen (NSO) compounds for the mineralized Kupferschiefer Spremberg-Graustein field in Eastern Germany based on samples from two drill cores. The study aims to help to better understand the role that organic matter plays during the mineralisation and formation of the sedimentary ore deposit within the Kupferschiefer with a focus on stable hydrogen isotope compositions and NSO compositional data to especially address the origin and to assess the oxidative nature of the brines that caused the mineralization in the Spremberg-Graustein field. The data publication includes bulk, compositional and stable isotope data on inorganic metals and organic matter. The data about metal contents were generated using ICP-MS while those on the organic matter were generated using Rock-Eval pyrolysis, a microscope, a Soxhlet apparatus, medium pressure liquid chromatography (MPLC), gas chromatography with flame ionization (GC-FID) and mass spectrometric detection (GC-MS), gas chromatography isotope ratio mass spectrometry (GC-IRMS) and ultrahigh resolution mass spectrometry (Fourier Transform ion cyclotron resonance mass spectrometry, FT-ICR-MS) with Electrospray ionization (ESI) and Atmospheric pressure photoionization (APPI). The full description of samples, methods and data is given in the following sections.

Keywords


Originally assigned keywords
Kupferschiefer
Permian
Organic Matter
NSO compounds
hydrogen exchange
metal porphyrins
compound specific stable hydrogen isotopic composition
FT-ICR-MS
EARTH SCIENCE > SOLID EARTH > EARTH GASES/LIQUIDS > PETROLEUM
EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY
EARTH SCIENCE > SOLID EARTH > ROCKS/MINERALS/CRYSTALS > METALS
EARTH SCIENCE > SOLID EARTH > ROCKS/MINERALS/CRYSTALS > SEDIMENTARY ROCKS

Corresponding MSL vocabulary keywords
Permian

MSL enriched keywords
Phanerozoic
Paleozoic
Permian
minerals
chemical elements
sulfur
equipment
mass spectrometer
isotope ratio mass spectrometer
gas chromatograph-mass spectrometer
inductively coupled plasma-mass spectrometer
measured property
oxygen
sulphur
ore mine

Metadata


MSL enriched sub domains

geochemistry

Resource Type

Dataset


Source


Source publisher

GFZ Data Services

DOI

10.5880/gfz.3.2.2022.001

Creators

Poetz, Stefanie
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Liu, Yang
Personal
School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China
Magnall, Joseph M.
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Vieth-Hillebrand, Andrea
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Yang, Shengyu
Personal
School of Geosciences, China University of Petroleum (East China), 266580 Qingdao, China
Göthel, Michael
Personal
LBGR Brandenburg State Office for Mining, Geology and Mineral Resources, Department Geology, Inselstraße 26, D-03046 Cottbus, Germany
Gleeson, Sarah A.
Personal
Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany | GFZ German Research Centre for Geosiences, Potsdam, Germany
Schulz, Hans-Martin
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Karger, Cornelia
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Noack, Doreen
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Günther, Kristin
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Kaminsky, Anke
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Rothe, Heike
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany

Contributors

Poetz, Stefanie
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Poetz, Stefanie
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Poetz, Stefanie
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Liu, Yang
Personal
School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China
Liu, Yang
Personal
School of Energy resources, China University of Geosciences (Beijing), 100083 Beijing, China
Magnall, Joseph M.
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Vieth-Hillebrand, Andrea
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Yang, Shengyu
Personal
School of Geosciences, China University of Petroleum (East China), 266580 Qingdao, China
Göthel, Michael
Personal
LBGR Brandenburg State Office for Mining, Geology and Mineral Resources, Department Geology, Inselstraße 26, D-03046 Cottbus, Germany
Gleeson, Sarah A.
Personal
Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany | GFZ German Research Centre for Geosiences, Potsdam, Germany
Schulz, Hans-Martin
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Karger, Cornelia
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Noack, Doreen
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Günther, Kristin
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Kaminsky, Anke
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Rothe, Heike
Personal
GFZ German Research Centre for Geosiences, Potsdam, Germany
Poetz
GFZ German Research Centre for Geosiences, Potsdam, Germany
Poetz
GFZ German Research Centre for Geosiences, Potsdam, Germany

Citation

Poetz, S., Liu, Y., Magnall, J. M., Vieth-Hillebrand, A., Yang, S., Göthel, M., Gleeson, S. A., Schulz, H.-M., Karger, C., Noack, D., Günther, K., Kaminsky, A., & Rothe, H. (2022). Organochemical characterization of the mineralized Kupferschiefer in Spremberg, East Germany: Compositional and isotope data on hydrocarbons, biomarker and NSO compounds (S. Poetz, Ed.) [Data set]. GFZ Data Services. https://doi.org/10.5880/GFZ.3.2.2022.001


References


Dates

Issued 2022

Language

- no language entry found -


Funding References

Funder Name National Natural Science Foundation of China
Funder Identifier https://doi.org/10.13039/501100001809
Award Number 42102171
Award Title Yang Liu

Rights

Name Creative Commons Attribution 4.0 International
URI https://creativecommons.org/licenses/by/4.0/legalcode
Identifier cc-by-4.0
Identifier Scheme SPDX
Scheme URI https://spdx.org/licenses/

Locations


Geo location(s)

Location of drillcore 121h/72

Location of drillcore 115a/71