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Data Publication

Calibration and Method Validation for Lead (Pb) Isotope Ratio Measurements performing by ThermoFisher Neptune Plus Mass Spectrometer in the NEPTUNE-TIMS Laboratory (Istituto di Geoscienze e Georisorse, CNR di Pisa)

Di Giuseppe, Paolo | Salvadori, Matteo | Dini, Andrea | Pennisi, Maddalena | Cornacchia, Irene | Vezzoni, Simone | Rielli, Andrea | Agostini, Samuele

GFZ Data Services

(2023)

We describe here in detail the results and the setup of the high precision Pb isotope ratio analysis performed by Multi Collector Inductively Coupled Plasma Mass Spectrometer (MC ICP MS), Thermo Scientific Neptune Plus TM. We performed this method adding thallium (Tl) as an internal isotopic standard to correct mass dependent isotopic fractionation. We also report the procedures for the chemical separat ion and purification of Pb from geological matri ces such as silicates , sulfides and historical artefacts . We report the data obtained on the international certified standard material SRM NIST 981 measured with MC ICP MS Neptune Plus, focusing on the accuracy and reproducibility of the analyses performed in the Neptune TIMS Laboratory (IGG-CNR in Pisa, Italy), and highlighting the advantages brought by the installation of this new mass spectrometer.

Keywords


Originally assigned keywords
Lead Isotopes
MCICPMS
NeptuneTIMS Laboratory
Isotope Ratios
EPOS
multiscale laboratories
geochemistry and microscopy
geochemistry data
GEOCHEMICAL PROPERTIES

Corresponding MSL vocabulary keywords
multicollector-inductively coupled plasma-mass spectrometer

MSL enriched keywords
equipment
mass spectrometer
multicollector-inductively coupled plasma-mass spectrometer
thermal ionization-mass spectrometer
measured property
thallium

MSL enriched sub domains i

geochemistry


Source publisher

GFZ Data Services


DOI

10.5880/fidgeo.2022.039


Authors

Di Giuseppe, Paolo

0000-0002-6209-9435

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Salvadori, Matteo

0000-0002-6614-9794

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Dini, Andrea

0000-0002-6781-7256

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Pennisi, Maddalena

0000-0002-5213-2879

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Cornacchia, Irene

0000-0002-5658-2367

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Vezzoni, Simone

0000-0003-4150-0039

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Rielli, Andrea

0000-0003-3486-8636

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy

Agostini, Samuele

0000-0002-2060-0359

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Pisa, Italy


References

Longerich, H. P., Fryer, B. J., & Strong, D. F. (1987). Determination of lead isotope ratios by inductively coupled plasma-mass spectrometry (ICP-MS). Spectrochimica Acta Part B: Atomic Spectroscopy, 42(1–2), 39–48. https://doi.org/10.1016/0584-8547(87)80048-4

10.1016/0584-8547(87)80048-4

Cites

Earth Processes: Reading the Isotopic Code. (1996). In A. Basu & S. Hart (Eds.), Geophysical Monograph Series. American Geophysical Union. https://doi.org/10.1029/gm095

10.1029/GM095

Cites


Contact

Di Giuseppe, Paolo

paolo.digiuseppe@igg.cnr.it

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Via Moruzzi, 1, 56124 Pisa, Italy

Agostini, Samuele

s.agostini@igg.cnr.it

Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Via Moruzzi, 1, 56124 Pisa, Italy


Citiation

Di Giuseppe, P., Salvadori, M., Dini, A., Pennisi, M., Cornacchia, I., Vezzoni, S., Rielli, A., & Agostini, S. (2023). Calibration and Method Validation for Lead (Pb) Isotope Ratio Measurements performing by ThermoFisher Neptune Plus Mass Spectrometer in the NEPTUNE-TIMS Laboratory (Istituto di Geoscienze e Georisorse, CNR di Pisa) [Data set]. GFZ Data Services. https://doi.org/10.5880/FIDGEO.2022.039